Szczepaniak’s Group Publications
(47) Heterogeneous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation
K. Kapil, M. Sun, T.C. Lin, H. Murata, G. Szczepaniak, K. Kim, S. DiLuzio, J. Jeong, M. Baumer, S. Bernhard, T. Kowalewski and K. Matyjaszewski
Polym. Chem., 2024, Advance Article, DOI: doi.org/10.1039/D4PY00899E
(46) Solid-Phase Synthesis of Well-Defined Multiblock Copolymers by Atom Transfer Radical Polymerization
G. Szczepaniak, K. Kapil, S. Adida, K. Kim, T.C. Lin, G. Yilmaz, H. Murata, K. Matyjaszewski*
J. Am. Chem. Soc., 2024, DOI: 10.1021/jacs.4c03675
(45) Hydrophilic Poly(meth)acrylates by Controlled Radical Branching Polymerization: Hyperbranching and Fragmentation
K. Kapil, A.M. Jazani, J. Sobieski, L.P. Madureira, G. Szczepaniak, M.R. Martinez, A. Gorczyński, H. Murata, T. Kowalewski, K. Matyjaszewski*
Macromolecules, 2024, DOI: 10.1021/acs.macromol.4c00408
(44) Aqueous photo-RAFT polymerization under ambient conditions: synthesis of protein–polymer hybrids in open air
A.M. Jazani, H. Murata, M. Cvek, A. Lewandowska-Andralojc, R. Bernat, K. Kapil, X. Hu, F. De Luca Bossa, G. Szczepaniak, K. Matyjaszewski
Chem. Sci., 2024, DOI: 10.1039/D4SC01409J
(43) Tailored Branched Polymer–Protein Bioconjugates for Tunable Sieving Performance
K. Kapil, H. Murata, G. Szczepaniak, A.J. Russell, K. Matyjaszewski*
ACS Macro Lett., 2024, 13, 4, 461–467, DOI: 10.1021/acsmacrolett.4c00059
(42) Visible-light-induced ATRP under high-pressure: synthesis of ultra-high-molecular-weight polymers
R. Bernat, G. Szczepaniak, K. Kamiński, M. Paluch, K. Matyjaszewski*, P. Maksym*
Chem. Commun., 2024, 60, 843-846, DOI: 10.1039/D3CC04982E
(41) Expanding the architectural horizon of nucleic-acid-polymer biohybrids by site-controlled incorporation of ATRP initiators in DNA and RNA
J. Jeong, G. Szczepaniak, S.R. Das*, K. Matyjaszewski*
Chem, 2023, 9, 11, 9, 3319-3334, DOI: 10.1016/j.chempr.2023.07.013
(40) Red-Light-Driven Atom Transfer Radical Polymerization for High-Throughput Polymer Synthesis in Open Air
X. Hu, G. Szczepaniak*, A. Lewandowska-Andralojc, J. Jeong, B. Li, H. Murata, R. Yin, A.M. Jazani, S.R. Das, K. Matyjaszewski*
J. Am. Chem. Soc., 2023, 145, 44, 24315–24327, DOI: 10.1021/jacs.3c09181
(39) Biomass RNA for the Controlled Synthesis of Degradable Networks by Radical Polymerization
J. Jeong, S.Y. An, X. Hu, Y. Zhao, R. Yin, G. Szczepaniak, H. Murata, S.R. Das*, K. Matyjaszewski*
ACS Nano, 2023, 17, 21, 21912–21922, DOI: 10.1021/acsnano.3c08244
(38) Reactivity Prediction of Cu-Catalyzed Halogen Atom Transfer Reactions Using Data-Driven Techniques
F. Lorandi*, M. Fantin*, H. Jafari, A. Gorczynski, G. Szczepaniak, S. Dadashi-Silab, A.A. Isse, K. Matyjaszewski*
J. Am. Chem. Soc., 2023, 145, 39, 21587–21599, DOI: 10.1021/jacs.3c07711
(37) RNA-polymer hybrids via direct and site-selective acylation with the ATRP initiator and photoinduced polymerization
J. Jeong, X. Hu, H. Murata, G. Szczepaniak, M. Rachwalak, A. Kietrys, S.R. Das*, K. Matyjaszewski*
J. Am. Chem. Soc., 2023, 145, 26, 14435–14445, DOI: 10.1021/jacs.3c03757
(36) Synthesis of RNA-Amphiphiles via Atom Transfer Radical Polymerization in the Organic Phase
J. Jeong, G. Szczepaniak, S.R. Das, K. Matyjaszewski*
Precis. Chem., 2023, 1, 5, 326–331, DOI: 10.1021/prechem.3c00042
(35) Fully Oxygen-Tolerant Visible-Light-Induced ATRP of Acrylates in Water: Toward Synthesis of Protein-Polymer Hybrids
K. Kapil, A.M. Jazani, G. Szczepaniak, H. Murata, M. Olszewski, K. Matyjaszewski*
Macromolecules, 2023, 56, 5, 2017–2026, DOI: 10.1021/acs.macromol.2c02537
(34) Synthesis of Tris [2‐(dimethylamino) ethyl] amine with Regiospecific Deuterium Labels
J. Sobieski, I. Ruzhylo, G. Szczepaniak, A. Gorczyński, K. Matyjaszewski, E. Manoury, R. Poli*
ChemistrySelect, 2023, 8, e20230005, DOI: 10.1002/slct.202300053
(33) Cu‐Catalyzed Atom Transfer Radical Polymerization: The Effect of Cocatalysts
M. Sun, G. Szczepaniak, S. Dadashi‐Silab, T.‐C. Lin, T. Kowalewski, K. Matyjaszewski*
Macromol. Chem. Phys., 2023, 224, 2200347, DOI: 10.1002/macp.202200347
(32) Visible‐Light‐Mediated Controlled Radical Branching Polymerization in Water
K. Kapil, G. Szczepaniak, M.R. Martinez, H. Murata, A.M. Jazani, J. Jeong, S.R. Das, Krzysztof Matyjaszewski*
Angew. Chem.Int. Ed., 2023, 62, e20221765, DOI: 10.1002/anie.202217658
(31) Blue‐light‐induced atom transfer radical polymerization enabled by iron/copper dual catalysis
D.J. Schild, J. Bem, G. Szczepaniak, A.M. Jazani, K. Matyjaszewski*
J. Polym. Sci., 2023, 61, 920–928, DOI: 10.1002/pol.20220633
(30) Alternating Methyl Methacrylate/n-Butyl Acrylate Copolymer Prepared by Atom Transfer Radical Polymerization
R. Yin, Y. Zhao, A. Gorczyński, G. Szczepaniak, M. Sun, L. Fu, K. Kim, H. Wu, M.R. Bockstaller*, K. Matyjaszewski*
ACS Macro Lett., 2022, 11, 10, 1217–1223, DOI: 10.1021/acsmacrolett.2c00517
(29) Sulfoxide-Containing Polyacrylamides Prepared by PICAR ATRP for Biohybrid Materials
M. Olszewski, J. Jeong, G. Szczepaniak, S. Li, A. Enciso, H. Murata, S. Averick, K. Kapil, S.R. Das, K. Matyjaszewski*
ACS Macro Lett., 2022, 11, 9, 1091–1096, DOI: 10.1021/acsmacrolett.2c00442
(28) Miniemulsion SI-ATRP by interfacial and ion-pair catalysis for the synthesis of nanoparticle brushes
R. Yin, P. Chmielarz*, I. Zaborniak, Y. Zhao, G. Szczepaniak, Z. Wang, T. Liu, Y. Wang, M. Sun, H. Wu, J. Tarnsangpradit, M.R. Bockstaller, K. Matyjaszewski*
Macromolecules, 2022, 55, 15, 6332–6340, DOI: 10.1021/acs.macromol.2c01114
(27) Controlled release of exosomes using atom transfer radical polymerization-based hydrogels
S.S. Yerneni, S. Lathwal, J. Cuthbert, K. Kapil, G. Szczepaniak, J. Jeong, S.R. Das*, P.G. Campbell*, K. Matyjaszewski*
Biomacromolecules, 2022, 23, 4, 1713–1722, DOI: 10.1021/acs.biomac.1c01636
(26) Red-light-induced, copper-catalyzed atom transfer radical polymerization
S. Dadashi-Silab, K. Kim, F. Lorandi, G. Szczepaniak, S. Kramer, L. Peteanu, K. Matyjaszewski*
ACS Macro Lett., 2022, 11, 3, 376–381, DOI: 10.1021/acsmacrolett.2c00080
(25) Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis
G. Szczepaniak*, J. Jeong, K. Kapil, S. Dadashi-Silab, S.S. Yerneni, P. Ratajczyk, S. Lathwal, D. Schild, S. Ranjan Das, K. Matyjaszewski*
Chem. Sci., 2022, 13, 11540-11550, DOI: 10.1039/D2SC04210J
(24) Kinetic comparison of isomeric oligo(ethylene oxide) (meth)acrylates: Aqueous polymerization of oligo(ethylene oxide) methyl ether methacrylate and methyl 2-(oligo(ethylene oxide) methyl ether)acrylate macromonomers
M.R. Martinez, S. Dworakowska, A. Gorczyński, G. Szczepaniak, F. De Luca Bossa, K. Matyjaszewski*
J. Polym. Sci., 2022, 60, 1887–1898, DOI: 10.1002/pol.20220086
(23) Conjugated cross-linked phenothiazines as green or red light heterogeneous photocatalysts for copper-catalyzed atom transfer radical polymerization
S. Dadashi-Silab, F. Lorandi, M.J. DiTucci, M. Sun, G. Szczepaniak, T. Liu, K. Matyjaszewski*
J. Am. Chem. Soc., 2021, 143, 25, 9630–9638, DOI: 10.1021/jacs.1c04428
(22) Making ATRP more practical: oxygen tolerance
G. Szczepaniak*, L. Fu, H. Jafari, K. Kapil, K. Matyjaszewski*
Acc. Chem. Res., 2021, 54, 7, 1779–1790, DOI: 10.1021/acs.accounts.1c00032
(21) Reflection on the Matyjaszewski Lab Webinar Series and the Rise of Webinars in Polymer Chemistry
F. Lorandi*, S. Lathwal, M.R. Martinez, S. Dadashi-Silab, G. Szczepaniak, J. Cuthbert
ACS Macro Lett., 2021, 10, 1, 54–59, DOI: 10.1021/acsmacrolett.0c00806
(20) Biocompatible photoinduced CuAAC using sodium pyruvate
J. Jeong, G. Szczepaniak*, S.S. Yerneni, F. Lorandi, H. Jafari, S. Lathwal, S.R. Das*, K. Matyjaszewski*
Chem. Commun., 2021, 57, 12844-12847, DOI: 10.1039/D1CC05566F
(19) Larger scale Stahl oxidation with instant Cu removal in convenient synthesis of chiral bidentate N–heterocyclic carbene precursor
K. Grudzień*, W. Nogaś, G. Szczepaniak, K. Grela*
Polyhedron, 2021, 199, 115090, DOI: 10.1016/j.poly.2021.115090
(18) p‐Substituted Tris(2‐pyridylmethyl)amines as Ligands for Highly Active ATRP Catalysts: Facile Synthesis and Characterization
A.E. Enciso, F. Lorandi, A. Mehmood, M. Fantin, G. Szczepaniak, B.G. Janesko, K. Matyjaszewski*
Angew.Chem.Int.Ed., 2020, 59, 14910–14920, DOI: 10.1002/anie.202004724
(17) Fully oxygen-tolerant atom transfer radical polymerization triggered by sodium pyruvate
G. Szczepaniak*, M. Łagodzińska, S. Dadashi-Silab, A. Gorczyński, K. Matyjaszewski*
Chem. Sci., 2020, 11, 8809-8816, DOI: 10.1039/D0SC03179H
(16) An isocyanide ligand for the rapid quenching and efficient removal of copper residues after Cu/TEMPO-catalyzed aerobic alcohol oxidation and atom transfer radical polymerization
G. Szczepaniak*, J. Piątkowski, W. Nogaś, F. Lorandi, S.S. Yerneni, M. Fantin, A. Ruszczyńska, A.E. Enciso, E. Bulska, K. Grela*, K. Matyjaszewski*
Chem. Sci., 2020,11, 4251-4262, DOI: 10.1039/D0SC00623H
(15) Iodine-mediated photoATRP in aqueous media with oxygen tolerance
Sajjad Dadashi-Silab, Grzegorz Szczepaniak, Sushil Lathwal, Krzysztof Matyjaszewski*
Polym. Chem., 2020, 11, 843-848, DOI: 10.1039/C9PY01650C
(14) A gentler touch: synthesis of modern ruthenium olefin metathesis catalysts sustained by mechanical force
N. Mukherjee, A. Marczyk, G. Szczepaniak, A. Sytniczuk, A. Kajetanowicz, K. Grela*
ChemCatChem, 2019, 11, 5362– 5369, DOI: 10.1002/cctc.201901444
(13) Impact of organometallic intermediates on copper-catalyzed atom transfer radical polymerization
M. Fantin, F. Lorandi, T.G. Ribelli, G. Szczepaniak, A.E. Enciso, C. Fliedel, L. Thevenin, A.A. Isse, R. Poli, K. Matyjaszewski*
Macromolecules, 2019, 52, 11, 4079–4090, DOI: 10.1021/acs.macromol.9b00870
(12) Preparation of well-defined polymers and DNA–polymer bioconjugates via small-volume eATRP in the presence of air
Y. Sun, S. Lathwal, Y. Wang, L. Fu, M. Olszewski, M. Fantin, A.E. Enciso, G. Szczepaniak, S. Das, K. Matyjaszewski*
ACS Macro Lett., 2019, 8, 5, 603–609, DOI: 10.1021/acsmacrolett.9b00159
(11) Semiheterogeneous purification protocol for the removal of ruthenium impurities from olefin metathesis reaction products using an isocyanide scavenger
G. Szczepaniak*, W. Nogaś, J. Piątkowski, A. Ruszczyńska, E. Bulska, K. Grela*
Org. Process Res. Dev., 2019, 23, 5, 836–844, DOI: 10.1021/acs.oprd.8b00392
(10) Ruthenium olefin metathesis catalysts systematically modified in chelating benzylidene ether fragment: experiment and computations
A. Zieliński, G. Szczepaniak, R. Gajda, K. Woźniak, B. Trzaskowski, D. Vidović, A. Kajetanowicz*, K. Grela*
Eur. J. Inorg. Chem., 2018, 3675–3685, 10.1002/ejic.201800639
(9) Highly efficient and time economical purification of olefin metathesis products from metal residues using an isocyanide scavenger
G. Szczepaniak*, A. Ruszczyńska, K. Kosiński, E. Bulska, K. Grela*
Green Chem., 2018, 20, 1280-1289, DOI: 10.1039/C7GC03324A
(8) High‐Performance Isocyanide Scavengers for Use in Low‐Waste Purification of Olefin Metathesis Products
G. Szczepaniak*, K. Urbaniak, C. Wierzbicka, K. Kosiński, K. Skowerski, K. Grela*
ChemSusChem, 2015, 8, 4139–4148, DOI: 10.1002/cssc.201500784
(7) Dialkylgallium Complexes with Alkoxide and Aryloxide Ligands Possessing N-Heterocyclic Carbene Functionalities: Synthesis and Structure
P. Horeglad*, O. Ablialimov, G. Szczepaniak, A.M. Dabrowska, M. Dranka, J. Zachara
Organometallics, 2014, 33, 1, 100–111, DOI: 10.1021/om400863y
(6) Towards “cleaner” olefin metathesis: Tailoring the NHC ligand of second generation ruthenium catalysts to afford auxiliary traits
G. Szczepaniak*, K. Kosiński*, K. Grela*
Green Chem., 2014, 16, 4474-4492, DOI: 10.1039/C4GC00705K
(5) The influence of organosuperbases on the structure and activity of dialkylgallium alkoxides in the polymerization of rac-lactide: the road to stereo diblock PLA copolymers
P. Horeglad*, A. Litwińska, G.Z. Żukowska, D. Kubicki, G. Szczepaniak, M. Dranka, J. Zachara
Appl. Organometal. Chem., 2013, 27, 328–336, DOI: 10.1002/aoc.2978
(4) Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand
C. Torborg, G. Szczepaniak, A. Zieliński, M. Malińska K. Woźniak, K. Grela*
Chem. Commun., 2013, 49, 3188-3190, DOI: 10.1039/C2CC37514A
(3) Easily removable olefin metathesis catalysts
K. Skowerski, C. Wierzbicka, G. Szczepaniak, Ł. Gułajski, M. Bieniek, K. Grela*
Green Chem., 2012, 14, 3264-3268, DOI: 10.1039/C2GC36015B
(2) Highly active catalysts for olefin metathesis in water
K. Skowerski*, G. Szczepaniak, C. Wierzbicka, Ł. Gułajski, M. Bieniek, K. Grela
Catal. Sci. Technol., 2012, 2, 2424-2427, DOI: 10.1039/C2CY20320K
(1) The first facile stereoselectivity switch in the polymerization of rac-lactide—from heteroselective to isoselective dialkylgallium alkoxides with the help of N-heterocyclic carbenes
P. Horeglad*, G. Szczepaniak, M. Dranka, J. Zachara
Chem. Commun., 2012, 48, 1171-1173, DOI: 10.1039/C2CC16072B